Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation

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Title:	Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation
Author:	Dorel, Ruth; de Mendoza, Paula; Calleja, Pilar; Pascual, Sergio; González-Cantalapiedra, Esther; Cabello, Noemí; Echavarren, Antonio M.
Abstract:	The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI‐MS.
Publication date:	2016-05-02
Subject(s):	Quimica
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	3171 p.
Document type:	Article Article - Draft
DOI:	10.1002/ejoc.201600311
Published by:	Eur. J. Org. Chem.
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