dc.contributor.author
Ferrer, Sofia
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2018-10-29T11:27:51Z
dc.date.accessioned
2024-04-23T10:22:51Z
dc.date.available
2018-10-29T11:27:51Z
dc.date.available
2024-04-23T10:22:51Z
dc.date.issued
2016-08-16
dc.identifier.uri
http://hdl.handle.net/2072/334733
dc.description.abstract
The gold(I)-catalyzed oxidative cyclization of 7-ethynyl-1,3,5-cycloheptatrienes gives 1-substituted barbar- alones in a general manner, which simplifies the access to other fluxional molecules. As an example, we report the shortest syntheses of bullvalene, phenylbullvalene, and disubstituted bullvalenes, and a readily accessible route to complex cage- type structures by further gold(I)-catalyzed reactions.
dc.format.extent
11178 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/draft
cat
dc.embargo.terms
12 mesos
cat
dc.identifier.doi
https://doi.org/10.1002/anie.201606101
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
