dc.contributor.author |
Ferrer, Sofia |
dc.contributor.author |
Echavarren, Antonio M. |
dc.date.accessioned |
2018-10-29T11:27:51Z |
dc.date.available |
2018-10-29T11:27:51Z |
dc.date.issued |
2016-08-16 |
dc.identifier.uri |
http://hdl.handle.net/2072/334733 |
dc.format.extent |
11178 p. |
dc.language.iso |
eng |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
54 |
dc.title |
Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/draft |
dc.subject.udc |
54 - Química |
dc.embargo.terms |
12 mesos |
dc.identifier.doi |
10.1002/anie.201606101 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
The gold(I)-catalyzed oxidative cyclization of 7-ethynyl-1,3,5-cycloheptatrienes gives 1-substituted barbar- alones in a general manner, which simplifies the access to other fluxional molecules. As an example, we report the shortest syntheses of bullvalene, phenylbullvalene, and disubstituted bullvalenes, and a readily accessible route to complex cage- type structures by further gold(I)-catalyzed reactions. |