dc.contributor.author
Zuzak, Rafal
dc.contributor.author
Dorel, Ruth
dc.contributor.author
Kolmer, Marek
dc.contributor.author
Szymonski, Marek
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2018-11-08T17:05:13Z
dc.date.accessioned
2024-04-23T10:51:06Z
dc.date.available
2019-05-23T02:45:05Z
dc.date.available
2024-04-23T10:51:06Z
dc.date.issued
2018-05-23
dc.identifier.uri
http://hdl.handle.net/2072/335525
dc.description.abstract
A unified approach to the synthesis of the series of higher acenes up to previously unreported undecacene has been developed through the on-surface dehydrogenation of partially saturated precursors. These molecules could be converted into the parent acenes by both atomic manipulation with the tip of a scanning tunneling and atomic force micro- scope (STM/AFM) as well as by on-surface annealing. The structure of the generated acenes has been visualized by high- resolution non-contact AFM imaging and the evolution of the transport gap with the increase of the number of fused benzene rings has been determined on the basis of scanning tunneling spectroscopy (STS) measurements.
dc.format.extent
10500 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Higher Acenes by On-Surface Dehydrogenation: From Heptacene to Undecacene
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/321066
cat
dc.identifier.doi
https://doi.org/10.1002/anie.201802040
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
