A Stereoconvergent Cyclopropanation Reaction of Styrenes

Author

del Hoyo, Ana M.

Herraiz, Ana G.

Garcia-Suero, Marcos

Publication date

2016-12-16



Abstract

The first stereoconvergent cyclopropanation reaction by means of photoredox catalysis using diiodomethane as methylene source is described. This transformation exhibits broad functional group tolerance and it is characterized by an excellent stereocontrol en route to trans-cyclopropanes regardless of whether E- or Z-styrene substrates were utilized.

Document Type

Article
Accepted version

Language

English

Subject

54

Pages

1610 p.

Documents

SueroCyclopropanation.docx

1.671Mb

 

Rights

L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/

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