dc.contributor.author
Carreras, Lucas
dc.contributor.author
Serrano-Torné, Marta
dc.contributor.author
W. N. M. van Leeuwen, Piet
dc.contributor.author
Vidal-Ferran, Anton
dc.date.accessioned
2019-05-20T15:16:42Z
dc.date.accessioned
2024-04-23T10:24:43Z
dc.date.available
2020-02-19T01:45:06Z
dc.date.available
2024-04-23T10:24:43Z
dc.date.issued
2019-02-19
dc.identifier.uri
http://hdl.handle.net/2072/355960
dc.description.abstract
The use of halogen bonding as a tool to construct the catalyst backbone is reported. Specifically, pyridyl- and iodotetrafluoroaryl-substituted phosphines were assembled in the presence of a rhodium(I) precursor to form the corresponding halogen-bonded complex XBphos-Rh. The presence of fluorine substituents at the iodo-containing supramolecular motif was not necessary for halogen bonding to occur due to the template effect exerted by the rhodium center during formation of the halogen-bonded complex. The halogen-bonded supramolecular complexes were successfully tested in the catalytic hydroboration of terminal alkynes.
dc.format.extent
3644 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
XBphos-Rh: A Halogen-Bond Assembled Supramolecular Catalyst
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.identifier.doi
https://doi.org/10.1039/c8sc00233a
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
