Title:
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Radical C-H-Amination of Heteroarenes using Dual Initiation by Visible Light and Iodine
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Author:
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Lucchetti, Nicola; Tkacheva, Anastasia; Fantasia, Serena; Muñiz, Kilian
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Abstract:
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A novel light-induced C─H amination of heteroarenes can be accomplished with preformed iodine(III) reagents as the combined oxidant and nitrogen source. The reaction requires the use of a small amount of molecular iodine, which under photochemical activation generates in situ an iodine(I) reagent as the initiator of the radical amination reaction. A total of 32 examples exemplify the broad scope of the transformation. |
Publication date:
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2018-10-18 |
Subject(s):
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54 |
Rights:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pages:
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3889 p. |
Document type:
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Article Article - Accepted version |
DOI:
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10.1002/adsc.201800677
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