dc.contributor.author |
Sopeña, Sergio |
dc.contributor.author |
Laserna, Victor |
dc.contributor.author |
Guo, Wusheng |
dc.contributor.author |
Martin, Eddy |
dc.contributor.author |
Escudero-Adán, Eduardo C. |
dc.contributor.author |
Kleij, Arjan W. |
dc.date.accessioned |
2019-05-22T14:19:00Z |
dc.date.available |
2019-05-22T14:19:00Z |
dc.date.issued |
2016-06-30 |
dc.identifier.uri |
http://hdl.handle.net/2072/356054 |
dc.format.extent |
2172 p. |
dc.language.iso |
eng |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
54 |
dc.title |
Highly Regio-Selective Organocatalytic formation of Carbamates from Substituted Cyclic Carbonates |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/acceptedVersion |
dc.embargo.terms |
12 mesos |
dc.identifier.doi |
10.1002/adsc.201600290 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
A highly regio-selective catalytic approach has been developed towards carbamates derived from cyclic organic carbonates by reaction of the latter with amine reagents under organo-catalytic control. For various combinations of carbonate and amine substrates, an organocatalyst (TBD: triazabicyclodecene) was used to increase the reaction kinetics while exerting excellent regio- selective control. The current method is the first general approach towards the control over the regio-selectivity of this reaction using a wide variety of easily accessed substituted organic carbonates. |