dc.contributor.author
Miralles, Núria
dc.contributor.author
Gómez, José Enrique
dc.contributor.author
Kleij, Arjan W.
dc.contributor.author
Fernández, Elena
dc.date.accessioned
2019-05-24T10:42:27Z
dc.date.accessioned
2024-04-23T10:40:03Z
dc.date.available
2019-05-24T10:42:27Z
dc.date.available
2024-04-23T10:40:03Z
dc.date.issued
2017-10-27
dc.identifier.uri
http://hdl.handle.net/2072/356271
dc.description.abstract
A method for the copper-catalyzed borylmethylation and borylation of vinyl cyclic carbonates through an SN2’ mech- anism is reported. These singular reactions involve selective SN2’ allylic substitutions with concomitant ring opening of the cyclic carbonate, and with extrusion of CO2 and formation of a useful hydroxyl functionality in a single step. The stereoselectivity of the homoallylic borylation and allylic borylation processes can be controlled, and synthetically useful unsaturated (E)-pent-2-ene-1,5- diols and (E)-but-2-ene-1,4-diols accessed.
dc.format.extent
6096 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Copper-mediated SN2’ Allyl-Alkyl and Allyl-Boryl Couplings of Vi- nyl Cyclic Carbonates
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.identifier.doi
https://doi.org/10.1021/acs.orglett.7b02947
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
