dc.contributor.author
Silvi, Mattia
dc.contributor.author
Melchiorre, Paolo
dc.date.accessioned
2019-07-09T08:52:59Z
dc.date.accessioned
2024-04-23T10:16:35Z
dc.date.available
2019-07-09T08:52:59Z
dc.date.available
2024-04-23T10:16:35Z
dc.date.issued
2018-02-01
dc.identifier.uri
http://hdl.handle.net/2072/358614
dc.description.abstract
Organocatalysis, catalysis mediated by small chiral organic molecules, is a powerful technology for enantioselective synthesis, and has found extensive applications within traditional ionic, two-electron-pair reactivity domains. Recently, organocatalysis has been successfully combined with photochemical reactivity to unlock previously inaccessible reaction pathways, thereby creating new synthetic opportunities. Here, we critically describe the historical context, scientific reasons, and landmark discoveries that were essential to expanding the functions of organocatalysis to include one- electron-mediated chemistry and excited-state reactivity.
dc.format.extent
41 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Enhancing the potential of enantioselective organocatalysis with light
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
6 mesos
cat
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/681840
cat
dc.identifier.doi
https://doi.org/10.1038/nature25175
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
