dc.contributor.author
Cañellas, Santiago
dc.contributor.author
Alonso, Pedro
dc.contributor.author
Pericas, Miquel A.
dc.date.accessioned
2020-01-21T12:25:12Z
dc.date.accessioned
2024-04-23T10:19:04Z
dc.date.available
2020-01-21T12:25:12Z
dc.date.available
2024-04-23T10:19:04Z
dc.date.issued
2018-08-01
dc.identifier.uri
https://hdl.handle.net/2072/368561
dc.description.abstract
The synthesis and application of a newly designed C2-symmetric chiral bifunctional triamine family (C2-CBT) is reported. These enantiopure chiral triamine scaffolds can be accessed in multigram amounts from simple amino acids while avoiding chromatographic purification. As a proof of principle, C2-CBT has been studied in the aldol reaction of cyclic ketones with isatins, with the target tertiary alcohols being formed in a highly efficient manner. Catalyst recovery by simple extraction techniques and subsequent reuse has been performed.
dc.format.extent
4806 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Development of C2-Symmetric Chiral Bifunctional Triamines: Synthesis and Application in Asymmetric Organocatalysis
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.relation.projectID
Grant No. CTQ2015- 69136-R (AEI/MINECO/FEDER, UE)
cat
dc.relation.projectID
Grant No. 2014SGR827
cat
dc.relation.projectID
SEV- 2013-0319
cat
dc.relation.projectID
BES- 2015-072152
cat
dc.identifier.doi
https://doi.org/10.1021/acs.orglett.8b01957
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
