SnS2/g-C3N4/graphite nanocomposites as durable lithium-ion battery anode with high pseudocapacitance contribution

Abstract

Altres ajuts: the CERCA Programme /Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program.

Tin disulfide is a promising anode material for Li-ion batteries (LIB) owing to its high theoretical capacity and the abundance of its composing elements. However, bare SnS suffers from low electrical conductivity and large volume expansion, which results in poor rate performance and cycling stability. Herein, we present a solution-based strategy to grow SnS nanostructures within a matrix of porous g-CN (CN) and high electrical conductivity graphite plates (GPs). We test the resulting nanocomposite as anode in LIBs. First, SnS nanostructures with different geometries are tested, to find out that thin SnS nanoplates (SnS-NPLs) provide the highest performances. Such SnS-NPLs, incorporated into hierarchical SnS/CN/GP nanocomposites, display excellent rate capabilities (536.5 mA h g at 2.0 A g) and an outstanding stability (∼99.7% retention after 400 cycles), which are partially associated with a high pseudocapacitance contribution (88.8% at 1.0 mV s). The excellent electrochemical properties of these nanocomposites are ascribed to the synergy created between the three nanocomposite components: i) thin SnS-NPLs provide a large surface for rapid Li-ion intercalation and a proper geometry to stand volume expansions during lithiation/delithiation cycles; ii) porous CN prevents SnS-NPLs aggregation, habilitates efficient channels for Li-ion diffusion and buffer stresses associated to SnS volume changes; and iii) conductive GPs allow an efficient charge transport.