dc.contributor.author
Pei, Xiao‐Li
dc.contributor.author
Pereira, Ana
dc.contributor.author
Smirnova, Ekaterina S.
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2021-03-24T10:13:13Z
dc.date.accessioned
2024-04-23T10:44:53Z
dc.date.available
2021-03-31T02:45:05Z
dc.date.available
2024-04-23T10:44:53Z
dc.date.issued
2020-03-31
dc.identifier.uri
http://hdl.handle.net/2072/447238
dc.description.abstract
Auration of o-trimethylsilyl arylphosphines leads
to the formation of gold and gold–silver clusters with orthometalated
phosphines displaying 3c–2e Au@C@M bonds
(M=Au/Ag). Hexagold clusters [Au6L4](X)2 are obtained by
reaction of (L@TMS)AuCl with AgX, whereas reaction with
AgX and Ag2O leads to gold–silver clusters [Au4Ag2L4](X)2.
Oxo-trigold(I) species [Au3O]+ were identified as the intermediates
in the formation of the silver-doped clusters. Other
[Au5], [Au4Ag], and [Au12Ag4] clusters were also obtained.
Clusters containing PAu@Au@AuP structural motif display
good catalytic activity in the
dc.format.extent
7309 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Small Gold(I) and Gold(I)–Silver(I) Clusters by C−Si Auration
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.relation.projectID
MINECO/FEDER, UE (CTQ2016-75960-P)
cat
dc.relation.projectID
Advanced Grant No. 835080
cat
dc.relation.projectID
Grant Agreement: 747170
cat
dc.relation.projectID
AGAUR (2017 SGR 1257)
cat
dc.identifier.doi
https://doi.org/10.1002/chem.202001509
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
