dc.contributor.author
Escofet, Imma
dc.contributor.author
Armengol-Relats, Helena
dc.contributor.author
Bruss, Hanna
dc.contributor.author
Besora, Maria
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2021-05-04T09:43:37Z
dc.date.accessioned
2024-04-23T10:43:54Z
dc.date.available
2021-05-04T09:43:37Z
dc.date.available
2024-04-23T10:43:54Z
dc.date.issued
2020-11-06
dc.identifier.uri
http://hdl.handle.net/2072/449891
dc.description.abstract
The nature of cyclopropyl gold(I) carbene‐type intermediates has been reexamined as part of a mechanistic study on the formation of cis‐ or trans‐fused bicyclo[5.1.0]octanes in a gold(I)‐catalyzed cascade reaction. Benchmark of DFT methods together with QTAIM theory and NBO analysis confirms the formation of distinct intermediates with carbenic or carbocationic structures in the cycloisomerizations of enynes.
dc.format.extent
15738 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
On the Structure of Intermediates in Enyne Gold(I)-Catalyzed Cyclizations: Formation of trans-Fused Bicyclo[5.1.0]octanes as a Case Study
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.relation.projectID
PID2019- 104815GB-I00
cat
dc.relation.projectID
CEX2019-000925-S
cat
dc.relation.projectID
Advanced Grant No. 835080
cat
dc.relation.projectID
2017 SGR 1257
cat
dc.identifier.doi
https://doi.org/10.1002/chem.202004237
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
