dc.contributor.author
Armengol-Relats, Helena
dc.contributor.author
Mato, Mauro
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2021-05-04T09:44:15Z
dc.date.accessioned
2024-04-23T10:44:00Z
dc.date.available
2021-05-04T09:44:15Z
dc.date.available
2024-04-23T10:44:00Z
dc.date.issued
2020-10-20
dc.identifier.uri
https://hdl.handle.net/2072/449892
dc.description.abstract
The formal (4+3) cycloaddition of 1,3‐dienes with Rh(II) and Au(I) non‐acceptor vinyl carbenes, generated from vinylcycloheptatrienes or alkoxyenynes, respectively, leads to 1,4‐cycloheptadienes featuring complex and diverse substitution patterns, including natural dyctiopterene C′ and a hydroxylated derivative of carota‐1,4‐diene. A complete mechanistic picture is presented, in which Au(I) and Rh(II) non‐acceptor vinyl carbenes were shown to undergo a vinylcyclopropanation/Cope rearrangement or a direct (4+3) cycloaddition that takes place in a non‐concerted manner.
dc.format.extent
1916 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Assembly of Complex 1,4‐Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non‐Acceptor Carbenes
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.relation.projectID
PID2019- 104815GB-I00
cat
dc.relation.projectID
CEX2019-000925-S
cat
dc.relation.projectID
Advanced Grant No. 835080
cat
dc.relation.projectID
2017 SGR 1257
cat
dc.identifier.doi
https://doi.org/10.1002/anie.202012092
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
