dc.contributor.author
Mato, Mauro
dc.contributor.author
Echavarren, Antonio M.
dc.date.accessioned
2021-05-11T07:28:15Z
dc.date.accessioned
2024-04-23T10:29:44Z
dc.date.available
2021-05-11T07:28:15Z
dc.date.available
2024-04-23T10:29:44Z
dc.date.issued
2018-12-18
dc.identifier.uri
http://hdl.handle.net/2072/449978
dc.description.abstract
Rhodium carbenes are key intermediates in a range of cycloadditions and insertion reactions. Herein, we report the first generation of donor RhII carbenes by decarbenation of 7‐substituted 1,3,5‐cycloheptatrienes. This discovery unlocks an improved retro‐Buchner‐cyclopropanation sequence, a Si−H insertion reaction for a broad‐scope synthesis of allylsilanes, and a new method for the vinylogation of aldehydes. The last strategy led to the development of an iterative synthesis of E‐polyenes, and to the total synthesis of navenones B and C.
dc.format.extent
2088 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
Donor Rhodium Carbenes by Retro-Buchner Reaction
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
12 mesos
cat
dc.relation.projectID
CTQ2016-75960-P
cat
dc.relation.projectID
2017 SGR 1257
cat
dc.identifier.doi
https://doi.org/10.1002/anie.201813512
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
