dc.contributor.author
Zhang, Liangliang
dc.contributor.author
Liu, Huilin
dc.contributor.author
Santiago, Tomás G.
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2025-12-01T13:32:39Z
dc.date.available
2025-12-01T13:32:39Z
dc.date.issued
2025-11-20
dc.identifier.uri
http://hdl.handle.net/2072/488974
dc.description.abstract
Herein, we disclose an enantioconvergent carbamoylation of racemic aziridines enabled by a dual catalytic strategy. The method offers a new entry point to highly enantioenriched β-amino amides from simple precursors and is characterized by its broad applicability, even with challenging combinations. Preliminary studies with well-defined nickel complexes support a scenario via carbamoyl organometallic intermediates.
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dc.publisher
ACS Publications
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dc.rights
Attribution 4.0 International
*
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
*
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
Química
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dc.title
Dual Catalytic Enantioconvergent Carbamoylation of Aziridines
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dc.type
info:eu-repo/semantics/article
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dc.description.version
info:eu-repo/semantics/publishedVersion
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dc.relation.projectID
FEDER/MCI PID2021-123801NB-I00
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dc.relation.projectID
PID2024-160739NB-I00/MICIU/AEI 10.13039/501100011033/FEDER,UE
ca
dc.relation.projectID
MCI/AIE (Severo Ochoa Excellence Accreditation 2002-2023 CEX2019-000925-S)
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dc.relation.projectID
L.Z. thanks Deutsche Forschungsgemeinschaft (DFG) for a postdoctoral fellowship
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dc.relation.projectID
H.L. thanks China Scholarship Council (CSC) for a predoctoral fellowship
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dc.identifier.doi
https://doi.org/10.1021/jacs.5c15873
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dc.rights.accessLevel
info:eu-repo/semantics/openAccess
