1. Home
  2. Universitat de Barcelona
  3. Química Inorgànica i Orgànica
  4. View Item

Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines

Author

Flores-Gaspar, Areli

Orgué Gassol, Sílvia

Grabulosa, Arnald

Riera i Escalé, Antoni

Verdaguer i Espaulella, Xavier

Publication date

2017-03-14T08:59:50Z

2017-03-14T08:59:50Z

2014-12-22

2017-03-14T08:59:50Z

Share

Abstract

In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.

Document Type

Article

Accepted version

Language

English

Subjects and keywords

Compostos organometàl·lics; Lligands (Bioquímica); Catàlisi asimètrica; Organometallic compounds; Ligands (Biochemistry); Enantioselective catalysis

Publisher

Royal Society of Chemistry

Related items

Versió postprint del document publicat a: https://doi.org/10.1039/c4cc09106j

Chemical Communications, 2014, vol. 51, p. 1941-1944

https://doi.org/10.1039/c4cc09106j

Recommended citation

This citation was generated automatically.

Export

DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

(c) Flores-Gaspar, Areli et al., 2014

This item appears in the following Collection(s)

ISGlobal - Institut de Salut Global de Barcelona [61470]

Química Inorgànica i Orgànica [1016]