dc.contributor.author
Ledezma Gairaud, Marisol
dc.contributor.author
Pineda, L.W.
dc.contributor.author
Aromí Bedmar, Guillem
dc.contributor.author
Sañudo Zotes, Eva Carolina
dc.date.issued
2020-03-30T10:15:14Z
dc.date.issued
2020-03-30T10:15:14Z
dc.date.issued
2015-06-09
dc.date.issued
2020-03-30T10:15:14Z
dc.identifier
https://hdl.handle.net/2445/154388
dc.description.abstract
Microwave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented.
dc.format
application/pdf
dc.publisher
Elsevier B.V.
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1016/j.ica.2015.05.030
dc.relation
Inorganica Chimica Acta, 2015, vol. 434, p. 215-220
dc.relation
https://doi.org/10.1016/j.ica.2015.05.030
dc.rights
cc-by (c) Mognon, Lorenzo et al.
dc.rights
http://creativecommons.org/licenses/by/3.0/es/
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject
Propietats magnètiques
dc.subject
Magnetic properties
dc.title
Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
