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A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response

Author

Vicente Castillo, Ramón

El Fallah El Boufrahi, Mohamed Salah

Casanovas Bayo, Berta

Font Bardia, Ma. Mercedes

Escuer Fité, Albert

Publication date

2020-05-14T17:30:00Z

2020-05-14T17:30:00Z

2016-06-20

2020-05-14T17:30:00Z

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Abstract

One new MnII 2MnIII 6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII 3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.

Document Type

Article

Accepted version

Language

English

Subjects and keywords

Geoquímica; Magnetisme; Estructura cristal·lina (Sòlids); Geochemistry; Magnetism; Layer structure (Solids)

Publisher

American Chemical Society

Related items

Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.6b00662

Inorganic Chemistry, 2016, vol. 55, num. 12, p. 5735-5737

https://doi.org/10.1021/acs.inorgchem.6b00662

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

(c) American Chemical Society , 2016

This item appears in the following Collection(s)

ISGlobal - Institut de Salut Global de Barcelona [61308]

Mineralogia, Petrologia i Geologia Aplicada [1068]