dc.contributor.author
Mayans Ayats, Júlia
dc.contributor.author
Sorace, Lorenzo
dc.contributor.author
Font Bardia, Ma. Mercedes
dc.contributor.author
Escuer Fité, Albert
dc.date.issued
2020-05-22T06:49:25Z
dc.date.issued
2021-09-15T05:10:19Z
dc.date.issued
2019-09-15
dc.date.issued
2020-05-22T06:49:25Z
dc.identifier
https://hdl.handle.net/2445/161998
dc.description.abstract
A new family of mononuclear lanthanide complexes with formula [LnIII(L)Cl3] (Ln = Eu (1), Tb (2), Dy (3), Er (4), Yb (5)) and L = N,N0-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(R,R/S,S)-ethane-1,2-diamine has been obtained employing enantiomerically pure Schiff bases. The complexes have been structurally characterized using X-ray single crystal and powder diffraction. Their dynamic magnetic properties have been studied showing that this family presents slow relaxation of the magnetization under certain conditions and confirms the different behavior of each LnIII cations in isostructural complexes: only the Er one possibly relaxing via an overbarrier Orbach process, while Raman process dominates for Dy and Yb derivative.
dc.format
application/pdf
dc.publisher
Elsevier Ltd
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2019.05.051
dc.relation
Polyhedron, 2019, vol. 170, p. 264-270
dc.relation
https://doi.org/10.1016/j.poly.2019.05.051
dc.rights
cc-by-nc-nd (c) Elsevier Ltd, 2019
dc.rights
http://creativecommons.org/licenses/by-nc-nd/3.0/es
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.title
Chiral mononuclear lanthanide complexes derived from chiral Schiff bases: Structural and magnetic studies
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
