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Anionic guests in prismatic cavities generated by enneanuclear nickel metallacycles

Author

Esteban Jarne, Jordi

Font Bardia, Ma. Mercedes

Escuer Fité, Albert

Publication date

2020-06-12T06:13:04Z

2020-06-12T06:13:04Z

2014

2020-06-12T06:13:04Z

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Abstract

The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni9} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.

Document Type

Article

Accepted version

Language

English

Subjects and keywords

Anions; Lligands; Compostos de coordinació; Magnetisme nuclear; Níquel; Anions; Ligands; Coordination compounds; Nuclear magnetism; Nickel

Publisher

American Chemical Society

Related items

Versió postprint del document publicat a: https://doi.org/10.1021/ic402651k

Inorganic Chemistry, 2014, vol. 53, num. 2, p. 1113-1121

https://doi.org/10.1021/ic402651k

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

(c) American Chemical Society , 2014

This item appears in the following Collection(s)

ISGlobal - Institut de Salut Global de Barcelona [61308]

Mineralogia, Petrologia i Geologia Aplicada [1068]