dc.contributor.author
Vlahopoulou, Gina
dc.contributor.author
Escuer Fité, Albert
dc.contributor.author
Font Bardia, Ma. Mercedes
dc.contributor.author
Calvet Pallàs, Maria Teresa
dc.date.issued
2024-04-19T06:18:25Z
dc.date.issued
2024-04-19T06:18:25Z
dc.date.issued
2024-04-19T06:18:30Z
dc.identifier
https://hdl.handle.net/2445/210180
dc.description.abstract
The use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported.
dc.format
application/pdf
dc.publisher
Elsevier B.V.
dc.relation
Versió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2011.11.037
dc.relation
Inorganic Chemistry Communications, 2012, vol. 16, p. 78-80
dc.relation
https://doi.org/10.1016/j.inoche.2011.11.037
dc.rights
(c) Elsevier B.V., 2012
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject
Química inorgànica
dc.subject
Estructura cristal·lina (Sòlids)
dc.subject
Inorganic chemistry
dc.subject
Layer structure (Solids)
dc.title
Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/acceptedVersion
