A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest

dc.contributor.author
Barrios Moreno, Leoní Alejandra
dc.contributor.author
Teat, Simon J.
dc.contributor.author
Roubeau, Olivier
dc.contributor.author
Aromí Bedmar, Guillem
dc.date.issued
2024-12-11T09:19:54Z
dc.date.issued
2024-12-11T09:19:54Z
dc.date.issued
2023-08-02
dc.date.issued
2024-12-11T09:19:54Z
dc.identifier
1359-7345
dc.identifier
https://hdl.handle.net/2445/217014
dc.identifier
739859
dc.description.abstract
A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.
dc.format
4 p.
dc.format
application/pdf
dc.language
eng
dc.publisher
Royal Society of Chemistry
dc.relation
Reproducció del document publicat a: https://doi.org/10.1039/d3cc02278a
dc.relation
Chemical Communications, 2023, vol. 59, p. 10628-10631
dc.relation
https://doi.org/10.1039/d3cc02278a
dc.rights
cc-by (c) L. A. Barrios et al., 2023
dc.rights
http://creativecommons.org/licenses/by/3.0/es/
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Articles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject
Òxids
dc.subject
Ferro
dc.subject
Química supramolecular
dc.subject
Oxides
dc.subject
Iron
dc.subject
Supramolecular chemistry
dc.title
A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/publishedVersion


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