2014-04-02T11:09:11Z
2014-04-02T11:09:11Z
2011
2014-04-02T11:09:11Z
This review deals with metal enolate-mediated stereoselective acetate aldol reactions. It summarizes recent advances on aldol additions of unsubstituted metal enolates from chiral auxiliaries, stoichiometric and catalytic Lewis acids, or acting in substrate- controlled reactions, which provide stereocontrolled aldol transformations that allow the efficient synthesis of structurally complex natural products.
Article
Accepted version
English
Reacció aldòlica; Productes naturals; Quiralitat; Catàlisi; Aldol reaction; Natural products; Chirality; Catalysis
Georg Thieme Verlag
Versió postprint del document publicat a: http://dx.doi.org/10.1055/s-0030-1260040
Synthesis. Journal of Synthetic Organic Chemistry, 2011, vol. 2011, num. 14, p. 2175-2191
http://dx.doi.org/10.1055/s-0030-1260040
(c) Georg Thieme Verlag, 2011