Stereoselective Acetate Aldol Reactions From Metal Enolates

Publication date

2014-04-02T11:09:11Z

2014-04-02T11:09:11Z

2011

2014-04-02T11:09:11Z

Abstract

This review deals with metal enolate-mediated stereoselective acetate aldol reactions. It summarizes recent advances on aldol additions of unsubstituted metal enolates from chiral auxiliaries, stoichiometric and catalytic Lewis acids, or acting in substrate- controlled reactions, which provide stereocontrolled aldol transformations that allow the efficient synthesis of structurally complex natural products.

Document Type

Article


Accepted version

Language

English

Publisher

Georg Thieme Verlag

Related items

Versió postprint del document publicat a: http://dx.doi.org/10.1055/s-0030-1260040

Synthesis. Journal of Synthetic Organic Chemistry, 2011, vol. 2011, num. 14, p. 2175-2191

http://dx.doi.org/10.1055/s-0030-1260040

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Rights

(c) Georg Thieme Verlag, 2011

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