Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis

All of RECERCAT

Use this identifier to quote or link this document: http://hdl.handle.net/2072/334733

Title:	Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis
Author:	Ferrer, Sofia; Echavarren, Antonio M.
Abstract:	The gold(I)-catalyzed oxidative cyclization of 7-ethynyl-1,3,5-cycloheptatrienes gives 1-substituted barbar- alones in a general manner, which simplifies the access to other fluxional molecules. As an example, we report the shortest syntheses of bullvalene, phenylbullvalene, and disubstituted bullvalenes, and a readily accessible route to complex cage- type structures by further gold(I)-catalyzed reactions.
Publication date:	2016-08-16
Subject (UDC):	54 - Química
Subject(s):	54
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	11178 p.
Document type:	Article Article - Draft
DOI:	10.1002/anie.201606101
Share:

Files	Size	Format
16.-Ferrer_et_a ... _International_Edition.pdf	1.944 MB	PDF