Título:
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Highly Regio-Selective Organocatalytic formation of Carbamates from Substituted Cyclic Carbonates
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Autor/a:
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Sopeña, Sergio; Laserna, Victor; Guo, Wusheng; Martin, Eddy; Escudero-Adán, Eduardo C.; Kleij, Arjan W.
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Abstract:
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A highly regio-selective catalytic approach has been developed towards carbamates derived from cyclic organic carbonates by reaction of the latter with amine reagents under organo-catalytic control. For various combinations of carbonate and amine substrates, an organocatalyst (TBD: triazabicyclodecene) was used to increase the reaction kinetics while exerting excellent regio- selective control. The current method is the first general approach towards the control over the regio-selectivity of this reaction using a wide variety of easily accessed substituted organic carbonates. |
Fecha de creación:
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30-06-2016 |
Materia(s):
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54 |
Derechos:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Páginas:
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2172 p. |
Tipo de documento:
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Artículo Artículo - Versión aceptada |
DOI:
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10.1002/adsc.201600290
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