Ligand-controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

Author

Moragas, Toni

Cornella, Josep

Martin,Ruben

Publication date

2014



Abstract

<p> A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO<sub>2</sub> has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.</p>

Document Type

Article

Language

English

Publisher

Journa of the American Chemical Society

Version of

J. Am. Chem. Soc.

Grant Agreement Number

info:eu-repo/grantAgreement/ERC/FP7/277883

MINECO (CTQ2012-34054 & Severo Ochoa Excellence Accreditation 2014-2018

SEV-2013-031

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the European Research Council

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Documents

Ni-cat regiodivergent carboxylation-final.pdf

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Rights

© 2014 American Chemical Society

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Papers [1245]