Ni-catalyzed Direct Reductive Amidation via C−O Bond Cleavage

dc.contributor.author
Correa, Arkaitz
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2018-01-15T16:04:48Z
dc.date.accessioned
2018-02-15T10:28:18Z
dc.date.accessioned
2024-04-23T10:30:55Z
dc.date.available
2018-01-15T16:04:48Z
dc.date.available
2018-02-15T10:28:18Z
dc.date.available
2024-04-23T10:30:55Z
dc.date.issued
2014
dc.identifier.uri
http://hdl.handle.net/2072/305835
dc.description.abstract
<p> &nbsp;</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A novel Ni-catalyzed reductive amidation</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> of C(sp<span style="font: 7.0px 'Times New Roman'">2</span>)&minus; and C(sp<span style="font: 7.0px 'Times New Roman'">3</span>)&minus;O electrophiles with isocyanates</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> is described. Such umpolung reaction allows for an unconventional</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> preparation of benzamides by using simple</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> starting materials and easy-to-handle Ni catalysts.</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> Within</p>
dc.language.iso
eng
dc.publisher
Journal of the American Chemical Society,
dc.relation
ICIQ
dc.relation
ERC
dc.relation
MICINN
dc.relation
ICIQ Foundation, European Research Council (ERC-277883) and MICINN (CTQ2012-34054) for
dc.relation.ispartof
J. Am. Chem. Soc.
dc.rights
© 2014 American Chemical Society
dc.title
Ni-catalyzed Direct Reductive Amidation via C−O Bond Cleavage
dc.type
info:eu-repo/semantics/article
dc.relation.projectID
info:eu-repo/grantAgreement/ERC/FP7/277883
dc.relation.projectID
(CTQ2012-34054)
dc.identifier.doi
https://doi.org/10.1021/ja5029793
dc.rights.accessLevel
info:eu-repo/semantics/openAccess


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