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Ni-catalyzed Direct Reductive Amidation via C−O Bond Cleavage

Author

Correa, Arkaitz

Martin, Ruben

Publication date

2014



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Abstract

<p> &nbsp;</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A novel Ni-catalyzed reductive amidation</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> of C(sp<span style="font: 7.0px 'Times New Roman'">2</span>)&minus; and C(sp<span style="font: 7.0px 'Times New Roman'">3</span>)&minus;O electrophiles with isocyanates</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> is described. Such umpolung reaction allows for an unconventional</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> preparation of benzamides by using simple</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> starting materials and easy-to-handle Ni catalysts.</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> Within</p>

Document Type

Article

Language

English

Publisher

Journal of the American Chemical Society,

Version of

J. Am. Chem. Soc.

Grant Agreement Number

info:eu-repo/grantAgreement/ERC/FP7/277883

(CTQ2012-34054)

Related items

ICIQ

ERC

MICINN

ICIQ Foundation, European Research Council (ERC-277883) and MICINN (CTQ2012-34054) for

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Ni-cat umpolung reductive amidation.pdf

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

© 2014 American Chemical Society

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Papers [1244]