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A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage

Author

Zarate, Cayetana

Martin, Ruben

Publication date

2014



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Abstract

<p> A Ni/Cu-catalyzed silylation of unactivated C&ndash;O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp<sup>2</sup>)<i>&minus;</i>O and even C(sp<sup>3</sup>)&ndash;O bonds with similar efficiency.</p>

Document Type

Article

Language

English

Publisher

Journal of the American Chemical Society,

Version of

J. Am. Chem. Soc.

Grant Agreement Number

info:eu-repo/grantAgreement/ERC/FP7/277883

(CTQ2012-34054)

Related items

ICIQ

ERC

MICINN

ICIQ Foundation, the European Research Council (ERC-277883) and MICINN (CTQ2012-34054)

Documents

Synergistic Ni-Cu C-O cleavage.pdf

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

© 2014 American Chemical Society

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Papers [1244]