dc.contributor.author |
Zarate, Cayetana |
dc.contributor.author |
Martin, Ruben |
dc.date.accessioned |
2018-01-15T16:04:48Z |
dc.date.accessioned |
2018-02-15T10:28:18Z |
dc.date.available |
2018-01-15T16:04:48Z |
dc.date.available |
2018-02-15T10:28:18Z |
dc.date.issued |
2014 |
dc.identifier.uri |
http://hdl.handle.net/2072/226393 |
dc.identifier.uri |
http://hdl.handle.net/2072/305836 |
dc.language.iso |
eng |
dc.publisher |
Journal of the American Chemical Society, |
dc.relation |
ICIQ |
dc.relation |
ERC |
dc.relation |
MICINN |
dc.relation |
ICIQ Foundation, the European Research Council (ERC-277883) and MICINN (CTQ2012-34054) |
dc.relation.ispartof |
J. Am. Chem. Soc. |
dc.rights |
© 2014 American Chemical Society |
dc.title |
A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage |
dc.type |
info:eu-repo/semantics/article |
dc.relation.projectID |
info:eu-repo/grantAgreement/ERC/FP7/277883 |
dc.relation.projectID |
(CTQ2012-34054) |
dc.identifier.doi |
https://dx.doi.org/10.1021/ja412107b |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp2)−O and even C(sp3)–O bonds with similar efficiency. |