dc.contributor.author
Zarate, Cayetana
dc.contributor.author
Martin, Ruben
dc.date.accessioned
2018-01-15T16:04:48Z
dc.date.accessioned
2018-02-15T10:28:18Z
dc.date.accessioned
2024-04-23T10:30:57Z
dc.date.available
2018-01-15T16:04:48Z
dc.date.available
2018-02-15T10:28:18Z
dc.date.available
2024-04-23T10:30:57Z
dc.identifier.uri
http://hdl.handle.net/2072/305836
dc.description.abstract
<p> A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp<sup>2</sup>)<i>−</i>O and even C(sp<sup>3</sup>)–O bonds with similar efficiency.</p>
dc.publisher
Journal of the American Chemical Society,
dc.relation
ICIQ Foundation, the European Research Council (ERC-277883) and MICINN (CTQ2012-34054)
dc.relation.ispartof
J. Am. Chem. Soc.
dc.rights
© 2014 American Chemical Society
dc.title
A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
dc.type
info:eu-repo/semantics/article
dc.relation.projectID
info:eu-repo/grantAgreement/ERC/FP7/277883
dc.relation.projectID
(CTQ2012-34054)
dc.identifier.doi
https://doi.org/10.1021/ja412107b
dc.rights.accessLevel
info:eu-repo/semantics/openAccess