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Ipso-Borylation of Aryl Ethers via Ni-catalyzed C–OMe Cleavage

Author

Zarate, Cayetana

Manzano, Rubén

Martin, Ruben

Publication date

2015



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Abstract

<p> A Ni-catalyzed <i>ipso-</i>borylation of aryl ethers via C(sp<sup>2</sup>)&ndash;OMe and C(sp<sup>3</sup>)&ndash;OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite divergence in site selectivity that can be easily switched by selecting the appropriate boron reagent.</p>

Document Type

Article

Language

English

Publisher

Journal of the American Chemical Society,

Version of

J. Am. Chem. Soc.

Grant Agreement Number

info:eu-repo/grantAgreement/ERC/FP7/277883

MINECO (CTQ2012-34054)

SEV-2013-0319)

Related items

ICIQ foundation

the European Research Council

MINECO

Severo Ochoa Excellence Accreditation

European Union

ERC

MINECO

Documents

Ipso borylation via C-OMe cleavage.pdf

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DIDL MARC MARC_CCUC METS OAI_DC ORE QDC RDF

Rights

© 2015 American Chemical Society

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Papers [1245]