Thermodynamic Stability of Heterodimetallic [LnLn′] Complexes: Synthesis and DFT Studies

Abstract

<div class="page" title="Page 1"> <div class="layoutArea"> <div class="column"> <p> <span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">The solid-state and solution configurations of the heterodimetallic complexes (Hpy)[LaEr(HL)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">(NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">)(py)(H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">O)] (</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR6'">1</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">), (Hpy)[CeEr(HL)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">(NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">)(py)(H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">O)] (</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR6'">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">), (Hpy)[CeGd(HL)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">(NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">)- (py)(H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">O)] (</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR6'">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">), (Hpy)[PrSm(HL)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">(NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">)(py)(H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">O)] (</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR6'">4</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">), and (Hpy)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">[LaYb(HL)</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">(NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">)(H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">2</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">O)](NO</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">) (</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR6'">5</span><span style="font-size: 9.000000pt; font-family: 'AdvMYR4'">), in which H</span><span style="font-size: 6.000000pt; font-family: 'AdvMYR4'; vertical-align: -2.000000pt">3</span><span style="font-siz