dc.contributor.author
G. Herraiz, Ana
dc.contributor.author
G. Suero, Marcos
dc.date.accessioned
2019-07-26T08:55:02Z
dc.date.accessioned
2024-04-23T10:37:55Z
dc.date.available
2019-12-08T02:45:05Z
dc.date.available
2024-04-23T10:37:55Z
dc.date.issued
2019-06-11
dc.identifier.uri
https://hdl.handle.net/2072/359749
dc.description.abstract
We describe the recent emergence of a new approach for the synthesis of
cyclopropane rings by means of photoredox catalysis. This methodology relies
on the photocatalytic generation of radical carbenoids or carbenoid-like
radicals as cyclopropanating species, and its characterized by an excellent
functional group tolerance, chemoselectivity and ability to cyclopropane E/Z
alkene mixtures with excellent stereocontrol. The mild reaction conditions and
the employ of user-friendly reagents are highly attractive features that may
find immediate use in academic and industrial laboratories.
dc.format.extent
2821 p.
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.title
New alkene cyclopropanation reactions enabled by photoredox catalysis via radical carbenoids
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/acceptedVersion
cat
dc.embargo.terms
6 mesos
cat
dc.identifier.doi
https://doi.org/10.1055/s-0037- 1611872
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
