Over the last decades, trifluoromethyl copper(I) complexes have played a key role as reactive species in the formation of C–CF3 bond-forming reactions. This Short Review covers not only select examples of relevant Cumediated or catalyzed nucleophilic trifluoromethylation reactions, one of the most active fields in organic synthesis, but also provides a comprehensive picture of the real behavior of these copper species, including ubiquitous cuprates, in the reaction media.
English
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2809 p.
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