Nucleophilic Trifluoromethylation Reactions Involving Copper(I) Species: From Organometallic Insights to Scope

Author

Mudarra, Ángel L.

Martínez de Salinas, Sara

Pérez-Temprano, Mónica H.

Publication date

2019-03-28



Abstract

Over the last decades, trifluoromethyl copper(I) complexes have played a key role as reactive species in the formation of C–CF3 bond-forming reactions. This Short Review covers not only select examples of relevant Cumediated or catalyzed nucleophilic trifluoromethylation reactions, one of the most active fields in organic synthesis, but also provides a comprehensive picture of the real behavior of these copper species, including ubiquitous cuprates, in the reaction media.

Document Type

Article
Accepted version

Language

English

Subject

54

Pages

2809 p.

Documents

Synthesis 2019, DOI- 10.1055s-0037-1611776.pdf

1.129Mb

 

Rights

L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/

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Papers [1244]