dc.contributor.author |
Sahoo, Basudev |
dc.contributor.author |
Bellotti, Peter |
dc.contributor.author |
Julià-Hern#ndez, Francisco |
dc.contributor.author |
Meng, Qing-Yuan |
dc.contributor.author |
Crespi, Stefano |
dc.contributor.author |
Kçnig, Burkhard |
dc.contributor.author |
Martin, Ruben |
dc.date.accessioned |
2020-03-04T09:43:04Z |
dc.date.available |
2020-03-04T09:43:04Z |
dc.date.issued |
2019-05-09 |
dc.identifier.uri |
http://hdl.handle.net/2072/373899 |
dc.format.extent |
9001 p. |
dc.language.iso |
eng |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
54 |
dc.title |
Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/acceptedVersion |
dc.embargo.terms |
cap |
dc.relation.projectID |
CTQ2015-65496-R |
dc.relation.projectID |
European Union Horizon 2020 under the Marie Sklodowska-Curie grant agreement (795961) |
dc.relation.projectID |
Elitenetzwerk Bayern (SynCat) |
dc.identifier.doi |
10.1002/chem.201902095 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
A photoinduced carboxylation of alkyl halides
with CO2 at remote sp3 C@H sites enabled by the merger
of photoredox and Ni catalysis is described. This protocol
features a predictable reactivity and site selectivity that
can be modulated by the ligand backbone. Preliminary
studies reinforce a rationale based on a dynamic displacement
of the catalyst throughout the alkyl side chain. |