Ni-catalyzed Direct Reductive Amidation via C−O Bond Cleavage

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Title:	Ni-catalyzed Direct Reductive Amidation via C−O Bond Cleavage
Author:	Correa, Arkaitz; Martin, Ruben
Abstract:	A novel Ni-catalyzed reductive amidation of C(sp2)− and C(sp3)−O electrophiles with isocyanates is described. Such umpolung reaction allows for an unconventional preparation of benzamides by using simple starting materials and easy-to-handle Ni catalysts. Within
Publication date:	2014
Rights:	© 2014 American Chemical Society
Document type:	Article
DOI:	https://dx.doi.org/10.1021/ja5029793
Published by:	Journal of the American Chemical Society,
Publish at:	J. Am. Chem. Soc.
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