Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2

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Use this identifier to quote or link this document: http://hdl.handle.net/2072/226398

dc.contributor.author	Wang, Xueqiang
dc.contributor.author	Liu, Yu
dc.contributor.author	Martin, Ruben
dc.date.accessioned	2018-01-15T16:04:50Z
dc.date.accessioned	2018-02-15T10:28:22Z
dc.date.available	2018-01-15T16:04:50Z
dc.date.available	2018-02-15T10:28:22Z
dc.date.issued	2015
dc.identifier.uri	http://hdl.handle.net/2072/226398
dc.identifier.uri	http://hdl.handle.net/2072/305841
dc.language.iso	eng
dc.publisher	Journal of the American Chemical Society,
dc.relation	iCIQ foundation
dc.relation	the European Research Council
dc.relation	MINECO
dc.relation	Severo Ochoa Excellence Accreditation
dc.relation	European Union
dc.relation	ERC, MINECO , COFUND,CELLEX
dc.relation.ispartof	J. Am. Chem. Soc
dc.rights	© 2015 American Chemical Society
dc.title	Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
dc.type	info:eu-repo/semantics/article
dc.relation.projectID	info:eu-repo/grantAgreement/ERC/FP7/277883
dc.relation.projectID	MINECO (CTQ2012-34054)
dc.relation.projectID	(SEV-2013-0319)
dc.identifier.doi	https://dx.doi.org/10.1021/jacs.5b03340
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	A user-friendly Ni-catalyzed reductive cyclization/carboxylation of unactivated alkyl halides with CO2 is described. The protocol operates under mild conditions with excellent chemoselectivity profile and a divergent syn/anti-selectivity pattern that can be easily modulated by the substrate utilized.

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